| Product Name | Epoxy Mica Intermediate Coating KF-MIO500 |
|---|---|
| Recommended Use | Epoxy Mica Intermediate CoatingSuitable For环氧云铁/Glass鳞片Intermediate Coat类RelatedIndustrialCoating ApplicationField/Area。 |
| Restricted Use | 仅限于IndustrialCoating ApplicationUsage。不可用于Food接触Surface、medical devicesCoating。 |
| 制造商 | Kexin New Materials (Guangdong) Co., Ltd. |
| Manufacturer | Foshan Shunde Mingbang Chemical Industry Co., Ltd. |
| Address | No. 19, Shilong Avenue, Xintang Industrial Zone, Lunjiao, Shunde District, Foshan City, Guangdong Province |
| Emergency telephone | +86-0757-88793275 |
| 网站 | https://www.psste.com |
Helaian Data Keselamatan (MSDS)
Material Safety Data Sheet · GB/T 16483-2008 · 共16章节
1 Chemicals and Enterprise Identification
2 Danger性概述
Signal word: Warning
🔥GHS02
❗GHS07
🌍GHS09
Hazard Statements
- Flam. Liq. 3: H226 Flammable liquid and vapor
- Skin Irrit. 2: H315 Causes skin irritation
- Eye Irrit. 2: H319 Causes serious eye irritation
- Skin Sens. 1: H317 May cause an allergic skin reaction
- STOT SE 3: H336 May cause drowsiness or dizziness
- Aquatic Chronic 2: H411 Toxic to aquatic life with long-lasting effects
Precautionary Statements
- P210: 远离热源/明火。禁止吸烟。
- P261: 避免Inhalation蒸气/喷雾。
- P280: 戴防护手套/护目镜/防护服。
- P302+P352: 如皮肤沾染:用大量肥皂和水清洗。
- P305+P351+P338: 如进入眼睛:用Water rinsing15分钟。取出隐形眼镜。继续冲洗。
- P333+P313: 如发生皮肤刺激/皮疹:就医。
- P403+P235: Storage在通风Good处。保持低温。
- P501: 按Danger废物法规处置。
3 Composition/Ingredient Information
| 化学物质 | CAS number | Concentration Range | GHSCategory |
|---|---|---|---|
| 环氧树脂 (Bisphenol A-Epichlorohydrin resin, MW≤700) | 25068-38-6 | 25-45% | Skin Irrit. 2 (H315), Eye Irrit. 2 (H319), Skin Sens. 1 (H317) |
| 改性胺/聚酰胺Curing Agent (Modified amine/polyamide hardener) | 68410-23-1 及类似 | 组分B: 35-55% | Skin Irrit. 2 (H315), Eye Irrit. 2 (H319), Skin Sens. 1B (H317) |
| 二甲苯 (Xylene, mixed isomers) | 1330-20-7 | 5-20% | Flam. Liq. 3 (H226), Acute Tox. 4 (H332), Skin Irrit. 2 (H315) |
| 正丁醇 (n-Butanol) | 71-36-3 | 2-8% | Flam. Liq. 3 (H226), Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335-H336) |
| 云母氧化铁 (Micaceous Iron Oxide, MIO, Fe₂O₃) | 1309-37-1 | 20-40% | 非Danger物质(惰性矿物颜料) |
| Glass鳞片 (Glass flakes, C-glass) | 65997-17-3 | 10-30% (Glass鳞片型) | 非Danger物质; 可能引起皮肤机械刺激(大粒径鳞片) |
4 First aid measures
Inhalation
移至新鲜空气处。如呼吸困难给氧。就医。
Skin Contact
用大量肥皂和水清洗。脱去污染衣物。如刺激持续就医。
Eye Contact
立即用清Water rinsing至少15分钟。就医。
Ingestion
不要催吐。用水漱口。立即就医。
Most important symptoms and effects:皮肤刺激/过敏、眼睛刺激、Inhalation蒸气头晕嗜睡。
Conditions requiring immediate medical attention:对症治疗，无特效解毒剂。
5 Firefighting measures
| Suitable extinguishing media | CO₂、干粉、泡沫、水雾 |
|---|---|
| Inappropriate Extinguishing Media | 直射水流 |
| Special hazards | 燃烧产生CO、CO₂、NOx、醛类。密闭容器受热可能破裂。 |
| Special protective equipment for firefighters | SCBA+全套防护服 |
消防废水围堵收集，勿排入水体。
6 Accidental release measures
Personnel Protection:穿戴PPE。清除点火源。Ensures通风。
Environment保护：Prevents进入下水道和水体。
Containment and Cleaning Methods:用惰性吸收材料(砂/蛭石)吸收。收集于密闭容器。
7 操作处置与Storage
Handling Precautions
在通风Good区域操作。远离热源/明火。避免皮肤和Eye Contact。Antistatic。
Storage Conditions
5-35°C阴凉通风。容器密闭。远离氧化剂和强酸。Shelf Life12 months。
8 Exposure controls/personal protection
| 物质 | PC-TWA | PC-STEL | Standard |
|---|---|---|---|
| 二甲苯 | 50 mg/m³ | 100 mg/m³ | GBZ 2.1-2019 |
| 正丁醇 | 100 mg/m³ | 200 mg/m³ | GBZ 2.1-2019 |
工程控制
充分通风+局部排风。Spraying在喷漆房内进行。
Personal Protective Equipment (PPE)
| Respiratory system | 有机蒸气/颗粒物Combination半面罩(A/P2) |
|---|---|
| Hand protection | 丁腈橡胶手套(≥0.4mm) |
| 眼部防护 | 防化学品护目镜 |
| Skin and body | 防化学品防护服 |
9 理化特性
| Appearance | 云铁灰色(特征银色/灰色)/ 各色(Glass鳞片型) |
|---|---|
| Odor | 特征性芳烃溶剂味 |
| Boiling point/boiling range | 136-144°C(溶剂) |
| Flash Point | 约25-30°C |
| Relative Density | 1.3-1.8 g/cm³ |
| Solubility | 不溶于水 |
| Viscosity | 60-120s (ISO 2431 4mm) |
| VOC content | <420 g/L |
10 Stability和反应性
| 反应性 | 正常条件下稳定。 |
|---|---|
| Chemical Stability | 推荐条件下稳定。 |
| Possibility of Hazardous Reactions | 与强氧化剂、强酸反应。大量Mixing放热。 |
| Conditions to avoid | High Temperature、明火、静电。 |
| Incompatible materials | 强氧化剂、强酸、强碱。 |
| Hazardous decomposition products | 燃烧:CO、CO₂、NOx、醛类。 |
11 Toxicological information
Acute Toxicity
| Route of exposure | 指标 | Test Species |
|---|---|---|
| oral ld50 | >2,000 mg/kg(大鼠) | |
| dermal ld50 | >2,000 mg/kg(兔) | |
| inhalation lc50 | >10 mg/L/4h(大鼠) |
Other Toxicological Information
| Skin corrosion/irritation | 引起皮肤刺激(H315)。 |
|---|---|
| Serious eye damage/eye irritation | 引起眼刺激(H319)。 |
| Respiratory or skin sensitization | 环氧树脂可能引起皮肤过敏(H317)。 |
| Carcinogenicity | 未Category为致癌物。IARC: 二甲苯Group 3。 |
| 特定靶器官毒性-单次接触 | Inhalation蒸气引起困倦/眩晕(H336)。 |
| Specific target organ toxicity - repeated exposure | 长期接触二甲苯可能影响CNS/肝/肾。 |
| Inhalation Hazard | 吞咽并进入呼吸道可能致命(含溶剂)。 |
12 Ecological information
Ecotoxicity
| 物种 | 指标 |
|---|---|
| fish 96h lc50 | 1-10 mg/L |
| daphnia 48h ec50 | 1-10 mg/L |
| algae 72h ec50 | 1-10 mg/L |
Persistence and Degradability
溶剂成分易生物降解。环氧树脂不易降解。
Bioaccumulation
低Bioaccumulation。
Mobility in Soil
溶剂中等移动性，树脂低移动性。
Other adverse effects
对水生生物有毒(H411)。
13 Disposal
Disposal method:HW12(涂料废物 900-299-12)+HW06(废有机溶剂 900-402-06)。送有资质Danger废物焚烧厂。
Disposal of contaminated packaging:未清空容器属Danger废物(HW49)。清空Metal容器可回收。
14 Transport Info
| UN编号 | UN1263 |
|---|---|
| 正式Transport名称 | 涂料 (Paint) |
| Transport hazard class | 第3类 易燃液体 |
| Packaging类别 | PG III |
| Environmental Hazards | 是(海洋污染物) |
| Special Precautions | Transport防破损、远离Food。 |
15 Regulatory Info
Chinese regulations
- GB/T 16483-2008
- GB 30000-2013
- GBZ 2.1-2019
- GB 30981-2020
- 《Danger化学品Safety管理条例》
- 《Danger化学品目录》(2015版)
- 《国家Danger废物名录》(2025版)
International regulations
- EU REACH (EC) 1907/2006
- EU CLP (EC) 1272/2008
- US OSHA HazCom 2012
- RoHS 2011/65/EU
16 其他信息
Revision date:2026-06-08
Version number:1.0
References
- ECHA Registered Substances Database (echa.europa.eu)
- NIOSH Pocket Guide to Chemical Hazards (cdc.gov/niosh/npg)
- PubChem Compound Database (pubchem.ncbi.nlm.nih.gov)
- GBZ 2.1-2019 Occupational Exposure Limits for Hazardous Agents in the Workplace - Chemical Hazardous Agents
- GBZ/T 195-2007 Occupational Health Management Standards for Organic Solvent Workplaces
- IARC Monographs on the Evaluation of Carcinogenic Risks to Humans
Abbreviations
GHS: Globally Harmonized System of Classification and Labelling of Chemicals; PC-TWA: Permissible Concentration-Time Weighted Average; PC-STEL: Short Term Exposure Limit; OEL: Occupational Exposure Limit; PPE: Personal Protective Equipment; LD₅₀: Lethal Dose 50%; LC₅₀: Lethal Concentration 50%; EC₅₀: Effect Concentration 50%; BCF: Bioconcentration Factor; Kow: Octanol-Water Partition Coefficient; SCBA: Self-Contained Breathing Apparatus; PBT: Persistent, Bioaccumulative and Toxic; vPvB: very Persistent and very Bioaccumulative; COA: Certificate of Analysis
Disclaimer:This MSDS is compiled based on public chemical databases such as ECHA, NIOSH, and PubChem, as well as typical industry formulations, and is for reference only. CAS numbers have been verified through public databases. The exact proportions of each component are the core technical secrets of the factory; this document expresses them as typical industry concentration ranges. Actual data should be based on factory batch test reports and product certificates of analysis (COA). Kexin New Materials assumes no legal liability arising from the use of the information in this MSDS. Users should independently assess the suitability and safety of the product under their specific conditions of use and comply with all applicable local laws and regulations. This document is prepared in accordance with the GB/T 16483-2008 standard and consists of 16 sections.
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