Epoxy zinc-rich primer Epoxy Zinc-Rich Primer
双组分环氧聚酰胺/锌粉重防腐底漆 — 牺牲阳极阴极保护
环氧富锌底漆(Epoxy Zinc-Rich Primer)是以环氧树脂与聚酰胺固化剂为成膜物、超细锌粉(干膜含量≥70%)为主要防锈颜料的高性能双组分防腐底漆。涂层通过锌粉对钢材的牺牲阳极阴极保护机制提供主动防腐——即使漆膜局部破损,周围锌粉仍持续为裸露钢材提供电化学保护。符合HG/T 3668-2020《环氧富锌底漆》2类标准,配套环氧云铁中间漆和聚氨酯/氟碳面漆后体系耐中性盐雾≥1000h,满足ISO 12944 C4-C5高腐蚀环境等级要求。广泛应用于跨海大桥、海上石油平台、石化储罐、输电铁塔、风电塔筒、大型钢结构厂房等重大工程的防腐底涂。
产品概述
Product Overview: Who is it suitable for? What problem does it solve?
环氧富锌底漆是为需要在C4-C5高腐蚀环境中获得15年以上长效防腐保护的钢结构而设计的重防腐底涂。它解决的核心问题是:普通防锈漆在沿海、化工大气、高湿等恶劣环境下3-5年即失效,而环氧富锌底漆通过"阴极保护+屏蔽防护"双重机制,配套中间漆和面漆后可提供15-25年的长效防护——大幅降低全寿命周期维护成本。
Product Definition
环氧富锌底漆(Epoxy Zinc-Rich Primer),中国标准编号HG/T 3668-2020,是以环氧树脂(双酚A型,CAS 25068-38-6)与聚酰胺固化剂(CAS 68410-23-1)为成膜物质、以超细球状锌粉(CAS 7440-66-6,粒径3-8μm,干膜中质量分数≥70%)为防锈颜料、以二甲苯/正丁醇为溶剂体系的双组分(2K)常温交联固化型防腐底漆。
Corrosion protection mechanism:涂层中高含量的锌粉颗粒之间及锌粉与钢材基体之间形成连续的导电通路。由于锌的标准电极电位(-0.76V vs SHE)低于铁(-0.44V),在腐蚀微电池中锌作为阳极优先发生氧化反应(Zn→Zn²⁺+2e⁻),释放的电子通过导电网络流向钢材表面,使钢材阴极极化至免蚀电位以下——这就是"牺牲阳极阴极保护"。同时,锌的腐蚀产物(ZnO、Zn(OH)₂、碱式碳酸锌等)逐渐填充涂层孔隙,形成致密的二次屏蔽层——"腐蚀产物自修复效应"。
Key performance data:
- The dry film zinc powder content is ≥70% (compliant with HG/T 3668-2020 Category 2).
- Volume solids content ≥60% (ISO 3233:1998)
- Pull-off adhesion ≥6 MPa (ISO 4624:2016, test doll diameter 20mm)
- Single coating resistance to neutral salt spray (NSS) ≥400h (ISO 9227:2022, rust width at the crisscrossing ≤2mm)
- The complete system (epoxy zinc-rich 80μm + epoxy micaceous iron oxide intermediate coat 150μm + polyurethane topcoat 80μm) has an NSS resistance of ≥1000h.
- Mixed application period: 4-8 hours (23°C, main agent: curing agent = 10:1 w/w)
Applicable substrates and limitations:适用于喷砂至Sa2.5级(ISO 8501-1:2007)的碳钢、低合金钢和铸铁基材。不推荐直接用于镀锌钢(锌层表面的钝化膜会阻隔导电通路——建议采用扫砂预处理或环氧底漆过渡)、不锈钢(表面钝化膜需先去除)、铝合金(电偶腐蚀风险——锌与铝的电位差过大)。施工温度限制:标准型5-40°C(低于5°C时环氧-胺交联反应速率极低,涂层固化不完全)。
Industry position and application:环氧富锌底漆是全球重防腐涂层体系(ISO 12944-5:2019体系A2.08/A3.08/A4.08等)中应用最广泛的底漆类型之一,与环氧云铁中间漆、聚氨酯/氟碳/聚硅氧烷面漆组成经典三重防护体系。典型应用工程包括:日本明石海峡大桥(1998年通车,设计寿命100年)、港珠澳大桥(2018年通车,50万m²钢箱梁)、北海海上石油平台(NORSOK M-501体系认证)等。据Grand View Research数据,2023年全球锌-rich底漆市场规模约28亿美元,亚太地区占48%份额。
产品特点

1. Cathodic protection (sacrificial anode) mechanism
涂层干膜含≥70%锌粉形成连续导电网络。锌的标准电极电位(-0.76V)低于铁(-0.44V),腐蚀发生时锌优先氧化(Zn→Zn²⁺+2e⁻),释放电子使钢材阴极极化至免蚀电位——即使涂层有3-5mm破损,周围锌粉仍可为裸露钢材提供持续电化学保护,这使环氧富锌底漆的防腐性能远超仅靠物理屏蔽的普通防锈底漆。

2. Superior corrosion resistance and durability
单涂层NSS≥400h(HG/T 3668 2类),配套环氧云铁中间漆+聚氨酯面漆后体系NSS≥1000h。ISO 12944-2的C5-M极高腐蚀环境(海洋飞溅区)下设计使用寿命15-25年。日本明石海峡大桥1998年采用环氧富锌底漆体系,至今25年以上涂层仍保持完好——实际使用寿命远超设计值。

3. Excellent compatibility
与环氧云铁中间漆(MIO屏蔽层)、聚氨酯面漆(耐候装饰层)、氟碳面漆(超耐候≥25年)、聚硅氧烷面漆(高耐候+高耐化学)均具有优异的层间附着力(拉开法≥5MPa)。环氧富锌底漆+环氧云铁中间漆+面漆是ISO 12944-5体系中最经典的重防腐三层配套方案——底漆提供阴极保护,中间漆提供厚度和物理屏蔽,面漆提供耐候和装饰。

4. Wide adaptability to construction
支持无气喷涂(喷嘴0.43-0.53mm,15-25MPa)、空气喷涂和刷涂/辊涂(小面积修补)。单道干膜60-80μm,混合比10:1(w/w),混合使用期4-8h(23°C)。宽温域施工(5-40°C),低温型配方可至-5°C。喷涂过程中需持续搅拌防止锌粉沉淀——建议使用带气动搅拌器的压力罐以确保涂料均匀性。

5. Shop Primer Solderability
专用配方(干膜15-25μm)可作为车间底漆——在钢结构预制厂涂装后,钢材仍可进行焊接和切割加工。焊接烟尘符合职业接触限值(GBZ 2.1-2019),焊缝X射线探伤合格率不受影响。适用于钢结构流水线自动化喷涂——喷涂后3-5min即可搬运堆垛。注意:仅专用车间底漆配方具有可焊性——标准型干膜60-80μm不适宜焊接。

6. Environmental Compliance · Global Standards
Complies with HG/T 3668-2020 (China) Standard Class 2, ISO 12944-5:2019 system numbers A2.08/A3.08/A4.08, NORSOK M-501:2022 (Norwegian Petroleum Industry) System 1, SSPC Paint 20 (USA) Zinc-rich Primer Type II (≥77% zinc powder). VOCs<420g/L(GB 30981-2020),可通过ROHS 2011/65/EU和REACH (EC) 1907/2006合规检测。产品碳足迹约2.8kg CO₂e/kg(摇篮到大门,SimaPro 9.5计算)——低于无机富锌底漆(3.5kg CO₂e/kg)。
技术参数
Physicochemical parameters
Drying and performance
· 2024年03月 国家涂料质量检验检测中心检测报告(编号:NTC-2024-0315-ZR)
· HG/T 3668-2020《环氧富锌底漆》第2类指标
· 本表数据为实验室标准条件下(23±2°C,50±5%RH)的典型值,实际数值因基材状态、施工工艺、环境条件可能略有差异。请联系技术支持获取批次COA(出厂检验报告)。
施工流程
Surface treatment
Sandblast to Sa2.5 (ISO 8501-1:2007), roughness Rz 40-75μm. Manual rust removal ≥ St3. Grease must be removed with SSPC-SP1 solvent. Primer application (RH) must be completed within 4 hours after sandblasting.<50%可延至8h)。禁忌:雨天/雾天/基材温度低于露点3°C时禁止施工。
Paint mixing
Stir the main agent for 3-5 minutes until the zinc powder is completely and evenly dispersed. Add the curing agent at a ratio of 10:1 (w/w) and continue stirring for 3-5 minutes. Let it stand for 15-30 minutes (23°C) to mature. Continuously stir during application to prevent zinc powder from settling—a pneumatic mixer is recommended. The mixed usable period is 4-8 hours (23°C). Do not dilute and use materials that have gelled beyond this period.
Primer application
Airless spraying (recommended): Nozzle 0.43-0.53mm/0.017-0.021", pressure 15-25MPa. Air spraying: Nozzle 1.5-2.0mm, pressure 0.3-0.5MPa. Brush/roller coating is only suitable for small-area pre-coating and repair. Single-coat DFT 60-80μm. Pre-coat welds, free edges, etc.
Drying and recoating
Surface dry ≤ 1h (23°C), hard dry ≤ 24h. Minimum recoating interval 8h (23°C). Maximum recoating interval 7d—exceeding this interval requires sandblasting (low pressure 0.2-0.3MPa, non-metallic abrasive) to remove surface zinc salts (basic zinc carbonate). Matching: Epoxy micaceous iron oxide intermediate coat 100-150μm → Polyurethane/fluorocarbon topcoat 50-80μm × 2.
Inspection and Acceptance
DFT measurement (ISO 2808:2019, SSPC-PA2): 80% of measuring points ≥ specified value, no measuring points<80%规定值。附着力检测(ISO 4624拉开法或ISO 2409划格法)。针孔检测(湿海绵法,67.5V/90V)。外观检查:无流挂/漏涂/起泡/缩孔/锌粉不均匀。
应用领域

Cross-sea/cross-river bridges
Steel box girder, bridge tower, arch rib

Offshore oil platforms
jacket, deck, living quarters

outer wall of petrochemical storage tank
Crude oil/refined oil/chemical storage tanks

Transmission towers/pipe towers
High-voltage/Ultra-high-voltage transmission line steel structure

Large steel structure factory building
Industrial plants and sports stadiums

Port machinery
Quay cranes, gantry cranes, ship unloaders

Wind turbine tower
Onshore/Offshore wind turbine towers

Naval Architecture and Ocean Engineering
Hull sections, ballast tanks, decks

Pipeline external corrosion protection
Oil and gas/water long-distance pipelines

Mining/Construction Machinery
Excavators, crushers, conveying equipment

Chemical/Refining Plant
Steel structure of reaction vessel, heat exchanger, and pipe gallery

Water treatment/water conservancy facilities
Wastewater treatment plant, sluice gate, trash rack
常见问题
下载中心
TDS Product Technical Specifications
Technical Data Sheet
Compliant with HG/T 3668-2020 standard
MSDS (Material Safety Data Sheet)
Material Safety Data Sheet
16 Chapters · GB/T 16483-2008
Color Card (Product Color Card)
Color Card
Steel gray/iron red standard color
Construction Application Guide
Application Guide
Complete construction guidance + defect countermeasures
工程案例

Corrosion Protection of Steel Box Girder of Akashi Kaikyo Bridge in Japan

Heavy-duty corrosion protection for jackets on offshore oil platforms in Beihai

Corrosion protection for ZPMC container quay cranes at Chennai Port, India

Corrosion Protection of Offshore Wind Farm Towers in the South China Sea
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